Persistent Link:
http://hdl.handle.net/10150/284416
Title:
Microwave spectra and structures of organometallic compounds
Author:
Drouin, Brian James
Issue Date:
1999
Publisher:
The University of Arizona.
Rights:
Copyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author.
Abstract:
The technique of pulsed-beam Fourier transform microwave spectroscopy is applied to gas-phase organometallic systems for elucidation of fundamental structural properties of the compounds. Ten organometallic species with significant catalytic and reactive properties are examined and presented. This work includes complete three-dimensional structural determinations of; methylrheniumtrioxide, cyclopentadienylthallium, tetracarbonyldihydroiron, tetracarbonyldihydroruthenium and tetracarbonylethyleneiron. Quadrupole coupling parameters are presented and discussed for the compounds; methylrheniumtrioxide, cyclopentadienylrheniumtricarbonyl, cyclopentadienylindium, 'anti' and ' syn' allyltricarbonylironbromide, chloroferrocene and bromoferrocene. Partial structural determinations are given for cyclopentadienylindium, ' anti' allyltricarbonylironbromide, chloroferrocene and bromoferrocene.
Type:
text; Dissertation-Reproduction (electronic)
Keywords:
Chemistry, Inorganic.; Chemistry, Physical.; Physics, Molecular.
Degree Name:
Ph.D.
Degree Level:
doctoral
Degree Program:
Graduate College; Chemistry
Degree Grantor:
University of Arizona
Advisor:
Kukolich, Stephen G.

Full metadata record

DC FieldValue Language
dc.language.isoen_USen_US
dc.titleMicrowave spectra and structures of organometallic compoundsen_US
dc.creatorDrouin, Brian Jamesen_US
dc.contributor.authorDrouin, Brian Jamesen_US
dc.date.issued1999en_US
dc.publisherThe University of Arizona.en_US
dc.rightsCopyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author.en_US
dc.description.abstractThe technique of pulsed-beam Fourier transform microwave spectroscopy is applied to gas-phase organometallic systems for elucidation of fundamental structural properties of the compounds. Ten organometallic species with significant catalytic and reactive properties are examined and presented. This work includes complete three-dimensional structural determinations of; methylrheniumtrioxide, cyclopentadienylthallium, tetracarbonyldihydroiron, tetracarbonyldihydroruthenium and tetracarbonylethyleneiron. Quadrupole coupling parameters are presented and discussed for the compounds; methylrheniumtrioxide, cyclopentadienylrheniumtricarbonyl, cyclopentadienylindium, 'anti' and ' syn' allyltricarbonylironbromide, chloroferrocene and bromoferrocene. Partial structural determinations are given for cyclopentadienylindium, ' anti' allyltricarbonylironbromide, chloroferrocene and bromoferrocene.en_US
dc.typetexten_US
dc.typeDissertation-Reproduction (electronic)en_US
dc.subjectChemistry, Inorganic.en_US
dc.subjectChemistry, Physical.en_US
dc.subjectPhysics, Molecular.en_US
thesis.degree.namePh.D.en_US
thesis.degree.leveldoctoralen_US
thesis.degree.disciplineGraduate Collegeen_US
thesis.degree.disciplineChemistryen_US
thesis.degree.grantorUniversity of Arizonaen_US
dc.contributor.advisorKukolich, Stephen G.en_US
dc.identifier.proquest9927528en_US
dc.identifier.bibrecord.b39570848en_US
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