The University of Arizona Campus Repository > Organizations > Geosciences > Geosciences Theses and Dissertations > Geosciences Theses >
Radius Effect of the Alkaline Earths on the Rate of Inversion of Aragonite to Calcite
- Persistent Link:
- Radius Effect of the Alkaline Earths on the Rate of Inversion of Aragonite to Calcite
- Issue Date:
- Copyright © is held by the author. Digital access to this material is made possible by the Antevs Library, Department of Geosciences, and the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author or the department.
- Collection Information:
- This item is part of the Geosciences Theses collection. It was digitized from a physical copy provided by the Antevs Library, Department of Geosciences, University of Arizona. For more information about items in this collection, please email the Antevs Library, firstname.lastname@example.org.
- The effect of magnesium, strontium, and other alkaline earths on the formation and persistence of metastable carbonates in the natural environment was investigated to determine the nature of the controlling mechanism. Barium and beryllium were studied to evaluate the effect of ionic radius; magnesium and strontium, in order to determine if the results correlate with the usual order of stability for complexes and adsorbed species. Known weights of aragonite were placed in contact with solutions of beryllium, magnesium, calcium, strontium, and barium. Samples were covered and periodically both pH and percent composition of aragonite determined; supernatant liquids and precipitates were analyzed for cation concentrations by atomic absorption spectroscopy and titrimetric methods. Results indicated that the order of effectiveness of alkaline earth metals in inhibiting recrystallization is : Be > Mg > Sr > Ba. This is the expected order of effectiveness for both surface and solution effects. A solution effect (i.e., sequestration of bicarbonate ions) is strongly suggested by the chemical behavior of each cation.
- text; Thesis-Reproduction (electronic)
- Degree Name:
- Degree Level:
- Degree Program:
- Degree Grantor:
- University of Arizona
- Committee Chair:
- Schreiber, Joseph F. Jr.
Full metadata record
All Items in UA Campus Repository are protected by copyright, with all rights reserved, unless otherwise indicated.