Surface Induced Dissociation (SID) as a Tool for Probing Halogenated Alkanethiolate Self-Assembled Monolayer Films and Reactivity of Polyatomic Ions

Persistent Link:
http://hdl.handle.net/10150/193316
Title:
Surface Induced Dissociation (SID) as a Tool for Probing Halogenated Alkanethiolate Self-Assembled Monolayer Films and Reactivity of Polyatomic Ions
Author:
Qi, Zhuhua
Issue Date:
2005
Publisher:
The University of Arizona.
Rights:
Copyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author.
Abstract:
Low energy (< 100 eV) ion-surface collisions of small polyatomic ions on halogen terminated alkanethiolate self-assembled monolayers were used to probe both the structure and the property of the organic thin films and the nature of the polyatomic ions. In Chapter 3, the conversion of a portion of the projectile ion’s kinetic energy to internal energy is proven to be dominantly determined by the mass of the terminal group. The main factor that determines the electron transfer process is the orientation and magnitude of the interface dipole instead of their ionization energy of the surface . Ionsurface reactions are predominantly determined by the nature of the film’s terminal group. In chapter 4, a peptide, YGGFLR, was used to perform soft landing on three different self-assembled monolayers at two collision energies, 5 eV and 30 eV. Successful soft landing was achieved on all three surfaces at only 30 eV collision energy.
Type:
text; Electronic Thesis
Keywords:
Chemistry
Degree Name:
MS
Degree Level:
masters
Degree Program:
Chemistry; Graduate College
Degree Grantor:
University of Arizona
Advisor:
Wysocki, Vicki H.
Committee Chair:
Wysocki, Vicki H.

Full metadata record

DC FieldValue Language
dc.language.isoENen_US
dc.titleSurface Induced Dissociation (SID) as a Tool for Probing Halogenated Alkanethiolate Self-Assembled Monolayer Films and Reactivity of Polyatomic Ionsen_US
dc.creatorQi, Zhuhuaen_US
dc.contributor.authorQi, Zhuhuaen_US
dc.date.issued2005en_US
dc.publisherThe University of Arizona.en_US
dc.rightsCopyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author.en_US
dc.description.abstractLow energy (< 100 eV) ion-surface collisions of small polyatomic ions on halogen terminated alkanethiolate self-assembled monolayers were used to probe both the structure and the property of the organic thin films and the nature of the polyatomic ions. In Chapter 3, the conversion of a portion of the projectile ion’s kinetic energy to internal energy is proven to be dominantly determined by the mass of the terminal group. The main factor that determines the electron transfer process is the orientation and magnitude of the interface dipole instead of their ionization energy of the surface . Ionsurface reactions are predominantly determined by the nature of the film’s terminal group. In chapter 4, a peptide, YGGFLR, was used to perform soft landing on three different self-assembled monolayers at two collision energies, 5 eV and 30 eV. Successful soft landing was achieved on all three surfaces at only 30 eV collision energy.en_US
dc.typetexten_US
dc.typeElectronic Thesisen_US
dc.subjectChemistryen_US
thesis.degree.nameMSen_US
thesis.degree.levelmastersen_US
thesis.degree.disciplineChemistryen_US
thesis.degree.disciplineGraduate Collegeen_US
thesis.degree.grantorUniversity of Arizonaen_US
dc.contributor.advisorWysocki, Vicki H.en_US
dc.contributor.chairWysocki, Vicki H.en_US
dc.identifier.proquest1437en_US
dc.identifier.oclc137355642en_US
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