SPONTANEOUS REACTIONS AND NEW COPOLYMERS FROM ELECTRON DEFICIENT, HIGHLY SUBSTITUTED OLEFINS.

Persistent Link:
http://hdl.handle.net/10150/188094
Title:
SPONTANEOUS REACTIONS AND NEW COPOLYMERS FROM ELECTRON DEFICIENT, HIGHLY SUBSTITUTED OLEFINS.
Author:
RIGHETTINI, ROBIN FRANCIS.
Issue Date:
1985
Publisher:
The University of Arizona.
Rights:
Copyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author.
Abstract:
The experimental results of the current work have three parts. First, the synthesis and characterization of several new copolymers by the free-radical copolymerization between several highly substituted electron-deficient olefins and furan, benzofuran, indene, alphamethylstyrene, and divinyl ether is discussed. Electron-poor olefins used included dimethyl cyanofumarate, carbomethoxymaleic anhydride and tricarbomethoxyethene. The spontaneous reactions of these monomer pairs were also investigated in both bulk and solution. Second, the effect of synthesis temperature on the composition of the previously reported (co)polymers of styrene with tricarbomethoxyethene and dimethyl dicyanofumarate are given. A ceiling temperature for the synthesis of this copolymer was found to be 220°C. Attempted copolymerization of tetracarbomethoxyethene gave evidence of a small but detectable amount of reaction. Finally, detailed procedures for the synthesis of dimethyl cyanofumarate, carbomethoxymaleic anhydride and tricarbomethoxyethene are given, including a new synthesis of carbomethoxymaleic anhydride.
Type:
text; Dissertation-Reproduction (electronic)
Keywords:
Alkenes -- Reactivity.; Polymers.; Polymerization.
Degree Name:
Ph.D.
Degree Level:
doctoral
Degree Program:
Chemistry; Graduate College
Degree Grantor:
University of Arizona

Full metadata record

DC FieldValue Language
dc.language.isoenen_US
dc.titleSPONTANEOUS REACTIONS AND NEW COPOLYMERS FROM ELECTRON DEFICIENT, HIGHLY SUBSTITUTED OLEFINS.en_US
dc.creatorRIGHETTINI, ROBIN FRANCIS.en_US
dc.contributor.authorRIGHETTINI, ROBIN FRANCIS.en_US
dc.date.issued1985en_US
dc.publisherThe University of Arizona.en_US
dc.rightsCopyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author.en_US
dc.description.abstractThe experimental results of the current work have three parts. First, the synthesis and characterization of several new copolymers by the free-radical copolymerization between several highly substituted electron-deficient olefins and furan, benzofuran, indene, alphamethylstyrene, and divinyl ether is discussed. Electron-poor olefins used included dimethyl cyanofumarate, carbomethoxymaleic anhydride and tricarbomethoxyethene. The spontaneous reactions of these monomer pairs were also investigated in both bulk and solution. Second, the effect of synthesis temperature on the composition of the previously reported (co)polymers of styrene with tricarbomethoxyethene and dimethyl dicyanofumarate are given. A ceiling temperature for the synthesis of this copolymer was found to be 220°C. Attempted copolymerization of tetracarbomethoxyethene gave evidence of a small but detectable amount of reaction. Finally, detailed procedures for the synthesis of dimethyl cyanofumarate, carbomethoxymaleic anhydride and tricarbomethoxyethene are given, including a new synthesis of carbomethoxymaleic anhydride.en_US
dc.typetexten_US
dc.typeDissertation-Reproduction (electronic)en_US
dc.subjectAlkenes -- Reactivity.en_US
dc.subjectPolymers.en_US
dc.subjectPolymerization.en_US
thesis.degree.namePh.D.en_US
thesis.degree.leveldoctoralen_US
thesis.degree.disciplineChemistryen_US
thesis.degree.disciplineGraduate Collegeen_US
thesis.degree.grantorUniversity of Arizonaen_US
dc.identifier.proquest8603151en_US
dc.identifier.oclc696815038en_US
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