MEASUREMENT OF HYPERFINE STRUCTURE IN DEUTERATED ACETYLENES VIA MOLECULAR-BEAM MICROWAVE SPECTROSCOPY.

Persistent Link:
http://hdl.handle.net/10150/185215
Title:
MEASUREMENT OF HYPERFINE STRUCTURE IN DEUTERATED ACETYLENES VIA MOLECULAR-BEAM MICROWAVE SPECTROSCOPY.
Author:
TACK, LESLIE MARTIN.
Issue Date:
1982
Publisher:
The University of Arizona.
Rights:
Copyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author.
Abstract:
This work describes the measurement of hyperfine structure in a series of deuterated acetylenes via molecular-beam microwave spectroscopy. Measurements of spin-rotation constants were used to calculate the paramagnetic contribution to the chemical shielding of the concerned nucleus. Where possible, comparisons with NMR measurements were made. Measurements of the deuterium quadrupole coupling determined in this work are compared with previous measurements on the same or similar systems. A review of the theoretical work done in this area is presented as well as a discussion of trends observed from high precision measurements of deuterium quadrupole coupling. A computer program that calculates hyperfine structure for up to four coupling nuclei of arbitrary spin is presented.
Type:
text; Dissertation-Reproduction (electronic)
Keywords:
Hyperfine structure.; Acetylene compounds -- Spectra.; Hyperfine structure -- Computer programs.
Degree Name:
Ph.D.
Degree Level:
doctoral
Degree Program:
Chemistry; Graduate College
Degree Grantor:
University of Arizona
Advisor:
Kukolich, S. G.

Full metadata record

DC FieldValue Language
dc.language.isoenen_US
dc.titleMEASUREMENT OF HYPERFINE STRUCTURE IN DEUTERATED ACETYLENES VIA MOLECULAR-BEAM MICROWAVE SPECTROSCOPY.en_US
dc.creatorTACK, LESLIE MARTIN.en_US
dc.contributor.authorTACK, LESLIE MARTIN.en_US
dc.date.issued1982en_US
dc.publisherThe University of Arizona.en_US
dc.rightsCopyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author.en_US
dc.description.abstractThis work describes the measurement of hyperfine structure in a series of deuterated acetylenes via molecular-beam microwave spectroscopy. Measurements of spin-rotation constants were used to calculate the paramagnetic contribution to the chemical shielding of the concerned nucleus. Where possible, comparisons with NMR measurements were made. Measurements of the deuterium quadrupole coupling determined in this work are compared with previous measurements on the same or similar systems. A review of the theoretical work done in this area is presented as well as a discussion of trends observed from high precision measurements of deuterium quadrupole coupling. A computer program that calculates hyperfine structure for up to four coupling nuclei of arbitrary spin is presented.en_US
dc.typetexten_US
dc.typeDissertation-Reproduction (electronic)en_US
dc.subjectHyperfine structure.en_US
dc.subjectAcetylene compounds -- Spectra.en_US
dc.subjectHyperfine structure -- Computer programs.en_US
thesis.degree.namePh.D.en_US
thesis.degree.leveldoctoralen_US
thesis.degree.disciplineChemistryen_US
thesis.degree.disciplineGraduate Collegeen_US
thesis.degree.grantorUniversity of Arizonaen_US
dc.contributor.advisorKukolich, S. G.en_US
dc.contributor.committeememberBarfield, Mikeen_US
dc.contributor.committeememberFeltham, Roberten_US
dc.contributor.committeememberBates, Roberten_US
dc.contributor.committeememberHeterington, Billen_US
dc.contributor.committeememberBernath, Peteren_US
dc.identifier.proquest8306000en_US
dc.identifier.oclc688223823en_US
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